Cl⁻Sampling & Laboratory Analysis

Chloride Profiling & Durability Modelling

Quantifying Corrosion Risk and Predicting Remaining Service Life

Technical Specifications
Sampling Interval10mm increments from exposure surface
Sampling DepthTypically 50–80mm or to reinforcement depth
Analysis MethodAcid-soluble chloride per AS 1012.20 / ASTM C1152
Threshold0.4–0.6% by weight of cement (typical initiation threshold)
Diffusion ModellingFick's second law, apparent Dₐ and Cₛ parameters
LaboratoryNATA-accredited partner facilities (ISO/IEC 17025)

Chloride profiling is the process of measuring chloride concentration at incremental depths within concrete to determine how far chloride ions have penetrated from the exposure surface and at what rate. This data is the primary input for durability modelling, mathematical prediction of when chloride concentration at the reinforcement depth will exceed the corrosion threshold and initiate steel corrosion.

For reinforced concrete structures in marine, coastal, or de-icing salt environments, chloride-induced corrosion is the dominant degradation mechanism. The question asset owners need answered is not "is there chloride in the concrete?", there almost always is, but "when will chloride reach a level that causes reinforcement corrosion, and what does that mean for the remaining useful life of the structure?" Chloride profiling and durability modelling answer this question quantitatively.

TRSC obtains chloride profiles by drilling powder samples at 10mm incremental depths from the exposure surface, typically to a depth of 50–80mm or to reinforcement depth, whichever is greater. Powder samples are submitted to NATA-certified laboratories for acid-soluble chloride determination to AS 1012.20. The resulting concentration-versus-depth profile is fitted to Fick's second law of diffusion to determine the apparent diffusion coefficient and surface chloride concentration, the two parameters needed to model future chloride penetration.

At 12 Creek Street, chloride profiling of the facade concrete demonstrated that chloride concentrations at reinforcement depth were well below the corrosion threshold, a finding that contradicted the conservative assumption of chloride-induced corrosion underlying the original remediation recommendation. This quantified evidence supported a significantly reduced remediation scope, directly saving the asset owner substantial unnecessary expenditure. This outcome illustrates the commercial value of measured data versus conservative assumption.

Technical Scope
chloride profilingdurability modellingservice life predictionchloride diffusionFick's lawcorrosion thresholdmarine concreteAS 3600
Direct Contact

Speak with an RPEQ-qualified structural engineer about deploying this technology on your asset.

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Applications

Corrosion Risk Quantification

Determining whether chloride concentration at reinforcement depth exceeds, approaches, or is well below the corrosion initiation threshold for the specific concrete and exposure conditions.

Residual Service Life Prediction

Mathematical modelling of chloride diffusion to predict when corrosion initiation will occur at reinforcement depth, the key input for remaining design life and maintenance planning decisions.

Maintenance Interval Optimisation

Using durability modelling to determine the optimal timing for protective treatments, coating renewal, or cathodic protection installation, avoiding premature intervention and late intervention alike.

Remediation Scope Verification

Verifying whether proposed remediation scope is proportionate to actual chloride penetration, ensuring intervention is neither over-conservative nor under-conservative.

Design Life Extension Assessment

Providing the quantified durability evidence needed to certify that a structure can safely continue in service beyond its original design life, based on measured deterioration rather than assumed deterioration.

Marine Infrastructure Assessment

Chloride assessment of concrete in tidal, splash, and atmospheric marine exposure zones, where chloride penetration rates vary significantly with exposure severity.

Frequently Asked Questions

What is the chloride corrosion threshold?

The commonly cited threshold for chloride-induced corrosion initiation is 0.4% chloride by weight of cement, though this varies with concrete quality, cement type, and environmental conditions. Some standards cite 0.06% by weight of concrete as an equivalent threshold. TRSC uses the threshold appropriate to the specific concrete and exposure conditions, and always reports chloride concentrations in consistent units for clarity.

How accurate is durability modelling?

Durability modelling using Fick's second law provides a reasonable estimate of chloride penetration trends over time, but it is a simplification of a complex process. Real chloride diffusion is affected by changes in concrete properties over time, wetting/drying cycles, temperature variation, and crack pathways. TRSC treats durability model outputs as indicative trends rather than precise predictions, and always applies engineering judgment to interpret model results in the context of other investigation findings.

How many chloride profiles are needed?

The number of profiles depends on the structure size, exposure variation, and the decisions that need to be supported. Marine structures with varying exposure zones (submerged, tidal, splash, atmospheric) require profiles in each zone. A minimum of three profiles per exposure zone is standard practice. TRSC typically extracts 6–20 profiles per investigation, with locations guided by half-cell potential mapping and visual assessment to capture the range of conditions present.

Can chloride ingress be stopped?

Chloride ingress can be significantly slowed by surface treatments (silane impregnation, coatings) that reduce moisture and chloride transport into the concrete. Cathodic protection systems can halt corrosion even in the presence of chloride above the threshold. However, chloride already within the concrete cannot be easily removed. The engineering response depends on how far chloride has penetrated, whether it has initiated corrosion, and the remaining useful life requirement for the structure.

Deploy Cl⁻ on your asset

Every investigation begins with a direct conversation with an RPEQ-qualified structural engineer. No sales intermediary, contact TRSC to discuss whether chloride profiling & durability modelling is appropriate for your structural question.

Chloride Profiling & Durability Modelling (Cl⁻) | TRSC