Petro.Sampling & Laboratory Analysis

Petrographic Analysis

Thin-Section Microscopy for Concrete and Masonry Characterisation

Technical Specifications
Section Thickness~0.03mm (30 microns) standard thin section
MicroscopyTransmitted light, polarised light, fluorescence (UV)
Magnification10× – 400× (optical microscopy)
Sample Size75mm diameter core or equivalent block sample
Turnaround2–4 weeks (specialist petrographic laboratory)
StandardsASTM C856, ASTM C457 (air voids), BS 1881-124

Petrographic analysis is the microscopic examination of concrete and masonry samples prepared as thin sections (slices approximately 0.03mm thick mounted on glass slides). Under polarised light microscopy, the internal structure of the material is revealed in detail, aggregate mineralogy, cement matrix condition, air void system, crack patterns, and evidence of deleterious chemical reactions. This level of detail is not available from any other test method.

For structural investigation, petrographic analysis answers questions that compressive strength testing cannot: why is the concrete in its current condition, and what is likely to happen next? Evidence of alkali-silica reaction (ASR), delayed ettringite formation (DEF), sulfate attack, freeze-thaw damage, and fire damage is visible in thin section and can be identified, classified, and assessed for severity by an experienced petrographer.

At the Victory Hotel, petrographic analysis of core samples from the 1855 colonial masonry and early concrete elements provided critical information about original construction materials, lime mortar composition, aggregate sources, and cement types, that directly informed the specification of compatible repair materials. For heritage structures, petrographic analysis is the definitive method for understanding original construction and ensuring that modern repairs are materially compatible.

TRSC submits samples to NATA-accredited petrographic laboratories and works with specialist petrographers who understand the structural engineering context of the analysis. Petrographic reports are integrated with other investigation findings, compressive strength, chloride content, carbonation depth, to build a complete picture of the concrete or masonry condition and its implications for structural performance.

Technical Scope
petrographic analysisthin-section microscopyASRalkali-silica reactionDEFconcrete microstructureASTM C856aggregate assessment
Direct Contact

Speak with an RPEQ-qualified structural engineer about deploying this technology on your asset.

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Applications

ASR / DEF Detection

Identifying alkali-silica reaction, delayed ettringite formation, and other deleterious chemical reactions through characteristic microstructural indicators visible in thin section.

Aggregate Assessment

Characterising aggregate mineralogy, reactivity potential, and condition, identifying reactive aggregates, weathered particles, and deleterious inclusions.

Cement Matrix Assessment

Evaluating the condition of the cement matrix, degree of hydration, microcracking, carbonation effects, and evidence of chemical attack on the binder phase.

Air Void Analysis

Measuring the air void system (total air content, spacing factor, specific surface) to assess freeze-thaw resistance and concrete quality.

Fire Damage Assessment

Identifying the depth and severity of fire damage through characteristic temperature-dependent changes in aggregate and cement matrix mineralogy visible in thin section.

Heritage Material Characterisation

Analysing historic mortar, concrete, and masonry materials to determine original composition for compatible repair specification, binder type, aggregate grading, and additives.

Frequently Asked Questions

When is petrographic analysis warranted?

Petrographic analysis is warranted when the cause of concrete deterioration is uncertain and cannot be determined by visual inspection or standard testing alone, when ASR or other deleterious reactions are suspected, when fire damage depth needs to be determined, or when heritage materials need to be characterised for compatible repair specification. TRSC recommends petrographic analysis when the investigation findings to date do not adequately explain the observed condition.

What is ASR and how does petrography detect it?

Alkali-silica reaction (ASR) is a chemical reaction between alkalis in the cement and reactive silica in certain aggregate types. It produces a gel that absorbs water and swells, causing internal cracking and expansion. In thin section, ASR is identified by characteristic gel deposits in cracks and voids, reaction rims around aggregate particles, and a pattern of internal microcracking that is distinctive from other damage mechanisms.

Can petrographic analysis determine concrete age?

Petrographic analysis cannot directly determine concrete age, but it can provide clues, cement type (Portland vs. blended), aggregate sourcing, air entrainment (or lack thereof), and mix characteristics that are indicative of construction era. Combined with documentary evidence and knowledge of construction practices, petrographic findings can support approximate dating of concrete elements.

Deploy Petro. on your asset

Every investigation begins with a direct conversation with an RPEQ-qualified structural engineer. No sales intermediary, contact TRSC to discuss whether petrographic analysis is appropriate for your structural question.

Petrographic Analysis (Petro.) | TRSC